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Thermodynamics - 4PMBTHE3

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  • Number of hours

    • Lectures : 10.0
    • Tutorials : 6.0
    • Laboratory works : ?
    • Projects : ?
    • Internship : ?
    ECTS : 1.5

Goals

Understanding and mastering of thermodynamics as a basis for stability studies and evolution conditions of physical and chemical systems.
Calculation of thermal balances (quantification of heat exchange for a reaction) in
association with a chemical process.
Study of equilibrium: forecast of equilibrium composition for a reactive mixture.
Prediction of the evolution of the system and determination of conditions for chemical
transformations.
Concepts applications to examples and phenomena of biological interest.

Contact Annie ANTONI

Content

Fundamental principles
System, properties, state functions, equations of states
The laws of thermodynamics: heat and work, spontaneous reaction, irreversible or reversible
process
Auxiliary functions and their applications
Enthalpy, Gibbs energy, chemical potential
Thermochemistry
Partial molar quantities
Quantities of reaction/formation
Bond energies
Chemical equilibrium
Criteria for equilibrium and spontaneous change
Activity
Equilibrium constant, law of mass action
Principles of coupled reactions
The behavior of solutions
Ideal and non-ideal solutions, Excess properties
Dilute solutions
Ionic solutions, colligative properties.



Prerequisites

No

Tests

Semester 7 - The exam is given in english only 

One recto-verso A4 sheet, calculator.



DS écrit 2h
Modalités d'examen : 1 feuille A4 recto-verso de notes personnelles + calculatrice autorisées

Additional Information

Semester 7 - This course is given in english only EN

Curriculum->BIOMED->Semester 7

Bibliography

P. Desre, F. Hodaj, Thermodynamique des Materiaux - Equilibres de Phases et Metastabilite, EDP Sciences, 2010.
B. Diu, C. Guthmann, D. Lederer, B. Roulet, Thermodynamique, Hermann, 2007.
D.R. Gaskell, Introduction to the Thermodynamics of Materials, Taylor Francis, 2003.
D. Haynie, Biological Thermodynamics, Cambridge University Press, 2005.
H-G. Lee, Chemical Thermodynamics for Metals and Materials, Imperial College Press, 2000.
C.H.P. Luis, Chemical Thermodynamics of Materials, Elsevier, 1983.
P. Papon, J. Leblond, Thermodynamique des Etats de la Matiere, Hermann, 1990.
M. Thellier, C. Ripoll, Bases Thermodynamiques de la Biologie cellulaire, Dunod, 1991.

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Date of update March 13, 2019

Grenoble INP Institut d'ingénierie Univ. Grenoble Alpes