Informations générales
Number of hours
- Lectures 22.0
- Projects 0
- Tutorials 22.0
- Internship 0
- Laboratory works 0
ECTSECTS
4.0
Goal(s)
This course covers 1/ materials for electrochemistry and 2/ electrochemical energy conversion and storage systems.
1/ Description of the main materials used in industrial electrochemical applications: physico-chemical characteristics and electrical conduction mechanisms.
2/ Economic, industrial and societal context, operating modes, technologies and sizing of batteries and fuel cells.
Content(s)
1/ Materials for electrochemistry
I - Electrolyte materials: ionic conductors
- Reminder: liquids/solids. Characteristic macroscopic quantities: diffusion coefficient....
- Electrolyte solutions: what makes a good solvent for electrochemistry? Conduction by a viscous friction model for dilute solutions.
- Polymer electrolytes: what are the charge carriers? Conduction by free-volume mechanism. Materials design
- Ionic solids: what are the charge carriers? Point defect model. Transport mechanism by “hopping”, activated hopping model (Arrhenius). Ceramics: role of grain boundaries and microstructural aspects.
II-” Electrode materials
- Notions of electrodes with internal redox couples
- Topochemical reactions
- Examples of host compounds
- Applications of electrode materials
TD: Non-stoichiometry by insertion, Negative and positive electrodes in lithium-ion batteries, Electrochromism
and,
2/ Electrochemical energy conversion and storage systems
I-Accumulators
-General introduction and background to electrochemical conversion and storage, industrial and social issues
-Areas of application: some use cases, economics, markets
-Electrochemistry for batteries
-Different technologies
-Factors influencing performance
-processes of Li-ion battery assembly
-Sizing
Prerequisites
Prerequisites
Advanced knowledge of electrochemistry (thermodynamics, kinetics, and electrochemical methods), materials (major classes of materials and properties), and process engineering (chemical reactors)
Test
Additional Information
This course brings 2.0 ECTS to students in Engineer APPRENTISSAGE MEP 2Y